Sometimes you can get that golden ambient light effect during a hyper localised storm fronts around mountainous plateaus, like thunder storms during dusk in the Himalayas, where the terrain cuts holes in the cloud cover. Very epic ambience:

https://stock.adobe.com/images/thunderstorm-in-the-mountains-panoramic-summer-landscape-with-enchanting-stormy-sky-storm-clouds-sunny-valley-and-small-rural-house-sunset-sunrise-landscape-with-beautiful-sky-stormy-weather/215244664